4: Crystal Growing

Crystals are some of the most beautiful naturally occurring objects. A quartz crystal looks as if the edges have been carved but on closer inspection growth lines can be seen covering the faces. These lines show that the crystal has been formed by the growth of one layer after another across the face. You can grow crystals in the lab using substances such as alum or copper sulphate. There is a limit to the amount of solid (solute) which will dissolve in water. When the solution cannot dissolve any more solute it is said to be a saturated solution. Crystals grow in a saturated solution that is allowed to cool down. Try some out for yourself.

What you will need


sodium chloride
copper sulphate
sodium sulphate
potassium chromium sulphate
(chrome alum)
iron sulphate
ammonium sulphate
potassium aluminium sulphate (alum)
potassium hexacyanoferrate(III)
forceps

eye protection
disposable gloves for handling crystals

weighing balance
filter funnels
filter paper
250cm3 beakers
evaporating basins
cotton thread
electrical wire (small gauge)
object to coat in crystals (e.g. a cross)
stirring rods

What you do


SMALL CRYSTALS

  1. Eye ProtectionHarmful
    To make small crystals of different varieties you need to warm 100cm3 of water and add the amounts of solute below. Stir until no more crystals will dissolve.
    sodium chloride 33g in 100cm3 water
    copper sulphate 30g in 100cm3 water
    sodium sulphate 20g in 100cm3 water
    potassium aluminium sulphate (alum) 39g in 100cm3 water
  2. Pour this saturated solution into a large evaporating basin and leave for several days to crystallise.

GROWING LARGE CRYSTALS FROM SMALL ONES

  1. Eye ProtectionWear GlovesHarmful
    Make a new saturated solution of copper sulphate and allow it to cool down.
  2. Place the dish or beaker of new saturated solution in a place where the temperature will vary as little as possible.
  3. Using forceps, pick out the best copper sulphate crystal from the evaporating basin.
  4. Drop this into the cold saturated solution and leave it for a few days.
  5. Using forceps, turn the crystal every day so that it can grow equally on all sides.
    The secret is to keep the solution in a place which is no warmer by day than by night.
  6. An alternative method of growing your crystals is to tie a piece of thread around the starting crystal, then suspend it in the cold saturated solution. Leave in a constant temperature environment. (Alum crystals also grow well using this method).
    WarningUse forceps or gloves to handle the crystals.
  7. You can grow crystals around a wire shape which can be suspended in the saturated solution. Crystals form best on rough surfaces, so use cotton-covered electrical wire or plain wire wrapped with thread or light string.

UNUSUAL CRYSTALS
  1. Dissolve 500g of potassium hexacyanoferrate(III) in 1dm3 of water. Allow this to cool to a manageable temperature and filter the solution while it is still slightly hot.
  2. Stand the object you want to coat in crystals in a beaker and pour the filtered solution into this so that it covers the object.
  3. Leave to cool. Crystals should start to form after a few hours.
Eye Protection
eye protection must be worn

Wear Gloves
wear gloves for handling crystals

Harmful
HARMFUL
copper sulphate
iron sulphate



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