16: Secret Writing

This is another type of ‘magic’ writing. You will write with a special invisible ‘ink’ and spray the writing with special chemical sprays. The writing only becomes visible when a chemical reaction takes place between the ‘ink’ and the spray.

What you will need


weighing balance
spray bottles
pin board for attaching paper to be sprayed, pins
small paint brushes
large sheets of chromatography paper
hairdryer (optional)
eye protection
disposable gloves
de-ionised water
potassium hexacyanoferrate(III) solution
copper sulphate solution
ammonium thiocyanate solution
iron(III) nitrate solution
ammonia solution
a few drops of phenolphthalein solution

What you do


  1. Eye Protection
    Write a message on the chromatography paper - you can use either a paint brush or a fountain pen. Choose your painting or writing solution from the table of ‘inks’ below.

    ‘ink’Spray Solution
    potassium hexacyanoferrate(III) solutioniron(III) nitrate
    ammonium thiocyanate solutionIron(III) Nitrate
    copper sulphate solutionammonia
    phenolphthalein solutionammonia

  2. Let your writing dry by leaving it in the air or using a hairdryer.
  3. Irritant and HarmfulHighly FlammableWarning
    Avoid spraying your hands! It might be a good idea to wear protective gloves. In any case wash your hands afterwards. Spray your writing with the appropriate spray solution from the table above and see what appears!
    The phenolphthalein solution is highly flammable, so make sure there are no naked flames in the lab.

OTHER THINGS YOU CAN DO
Write a secret message to your friend with a combination of ‘inks’. They will have to try both spray solutions to see what you have written!

Eye Protection
eye protection must be worn

Warning
wear disposable gloves and wash your hands afterwards

Harmful
HARMFUL
copper sulphate solution

Irritant
IRRITANT
iron(III) nitrate solution

Highly Flammable
HIGHLY FLAMMABLE
phenolphthalein solution


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